Product ID:EPA TCLP ACIDS MIX, 48142
MSDS Date:05/13/1994
FSC:6630
NIIN:00N066607
MSDS Number: BZSBN

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

(ORAL,RAT) 121 MG/KG.

CAS: 95-48-7

RTECS: GO6300000

Fraction By Weight: 0.1%

OSHA PEL 5 PPM (MFR)

ACGIH TLV: 5 PPM (MFR)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-CRESOL; (3-METHYLPHENOL) (SARA 313) (CERCLA).

CAS: 108-39-4

RTECS: GO6125000

Fraction By Weight: 0.1%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL,RAT) 207 MG/KG.

CAS: 106-44-5

RTECS: GO6475000

Fraction By Weight: 0.1%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PHENOL, 2,4,5-TRICHLORO-; (PHENOL, 2,4,5-TRICHLORO-) (SARA

CAS: 95-95-4

RTECS: SN1400000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHENOL, 2,4,6-TRICHLORO-; (PHENOL, 2,4,6-TRICHLORO-) (SARA

CAS: 88-06-2

RTECS: SN1675000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHENOL, PENTACHLORO-; (PHENOL, PENTACHLORO-) (SARA 313)

CAS: 87-86-5

RTECS: SM6300000

Fraction By Weight: 0.1%

OSHA PEL 0.5 MG/M3, S

ACGIH TLV: 0.5 MG/M3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA).

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.4%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50:(ORAL,RAT) 5628 MG/KG (& SEE INGS)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. LOW BLOOD PRESSURE (HYPOTENSION). DERMATITIS,
BREATHING DIFFICULTY, HEADACHE, NAUS EA, DIZZINESS,
GASTROINTESTINAL DISTURBANCES. DEPRESSES CENTRAL NERVOUS SYSTEM.
NARCOSIS. LIVER DAMAGE.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:PHENOL, 2,4,6-TRICHLORO-:IARC
MONOGRAPHS, SUPP, VOL 7, PG 154, 1987:ANIMAL SUFFICIENT EVID. NTP
7TH ANNUAL RPT (SUPDAT)
Effects of Overexposure:HLTH HAZ:KIDNEY DAMAGE. REPORTED ANIMAL
CARCINOGEN. RESPIRATORY FAILURE, BLINDNESS. MAY CAUSE CORNEAL
INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LST 15 MINS. CONT MD. SKIN:FLUSH
W/LG VOLS OF WATER. WASH CLTHG & SHOES BEFORE REUSING. INHAL:IMMED
MOVE TO FRESH AIR. GIVE OXYGEN IF BRTHG IS LABORED. IF BRTHG STOPS,
GIVE A RTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERS. NEVER TRY TO MAKE UNCON PERS VOMIT. GIVE 2 TBSPS OF
BAKING SODA IN GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO
(SUPP DATA)

Flash Point:50.0F,10.0C
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION: CARBON MONOXIDE,
FORMALDEHYDE, HYDROGEN CHLORIDE.

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES. AVOID EYE OR
SKIN CONTACT. AVOID BREATHING VAPORS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:ON CARCINS, 1994:ANTIC TO BE CARCIN. ANIMAL:SKIN, EYE,
CNS, LIVER, KIDNEY EFTS. FIRST AID PROC:INDUCE VOMITING.
IMMEDIATELY CONTACT MD.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79 (H*2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100%
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:10

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE,
PERCHLORIC ACIDS, ALUMINUM & MAGNESIUM, METALS.
Hazardous Decomposition Products:CARBON MONOXIDE, FORMALDEHYDE,
HYDROGEN CHLORIDE.

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.